Archived posting to the Leica Users Group, 2003/06/23

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Subject: Re: [Leica] Mark Rabiner's Xtol instructions
From: Mark Rabiner <mark@rabinergroup.com>
Date: Mon, 23 Jun 2003 20:55:34 -0700
References: <LNBBLBNFHNEHGFKFMALGIEOIGDAB.tim@KairosPhoto.com>

Tim Atherton wrote:
> 
> I've been trying to search the archives for Mark's instructions on how he
> stores Xtol... but the archives don't seem to produce any posts prior to
> 2003?
> 
> Anyone have the message? (Mark?)
> 
> + anyone know why I'm only getting 2003 posts back?
> 
>

A Bark from Mark:

The people from the Smithsonian were nice enought to send over some of
my old papers in the vacume tube. Here they are in free flow form! Taken
from a bunch of posts, I took the quotes out and made the line endings
not short.


People seem have have trouble believing this concept and get lazy on it.
Their Xtol is sitting there in half filled bottles. Lots of "failures"
I've heard about on the internet have been from that. Lots. I can tell
you what works for me is pouring out my Xtol into 250 ml bottles which
are used as one shots in one liter metal tanks. There is no temptation
to have your xtol oxidize in a partially filled bottle. Another thing i
though of last week is what if your container you mix up your Xtol in
had some fixer in it or something else. It could be Xtol has less
tolerance to contamination. I use a mixing container marked "Xtol." it's
the only chemical that gets poured in there. I generally do that with
all fixers and developers.

100 ml per roll minimum stock only so far seem to apply to T Max 100 or
Delta 3200 which develop to extinction and cant pick up enough density
no matter how much longer you give it. If i were you I'd not use the
small can for anything. I use mine to scoop Sulfite. Never run anything
smaller than a one liter tank. Shot 4 quick rolls and run it in the
liter tank. Which film? Email me for times or call me. Get the 5 liter
Xtol not the 1 liter. Get 5 - 1 liter brown glass bottles from a
laboratory supply company and a few half and quarter liter ones, get a 8
liter 3 dollar plastic bucket to mix up your Xtol at room temperature
and pour it into those bottles with a nice little funnel. Have them all
marked "Xtol" ahead of time. In a one liter tank you can use quarter
liter bottles of Xtol as one-shots. Line them all up on your darkroom
shelf they will make you feel good. As i run lots of 2 liter tanks i
have lots of half liter bottles pre poured out.
I pour out

 6 large 500 ml bottles for processing 2 liter tanks

 8 small 250 ml bottles for processing 1 liter tanks

__________________________________
 
Dont order the one liter. They have problems. Order the 5 liter and aslo
order 5 one liter glass bottles and a few half and quarter liter
bottels. you cant store the stuff with air in the bottles they have to
be ALWAYS filled to the top. you to get into xtol you have to do the
thing with the bottles. some use a wine bladder but that does not appeal
to me. I've got a line of bottles all marked "Xtol" on my self. AS i go
1:3 and often use 2 liter tanks i mix up 6 large 500ml bottles for
processing 2 liter tanks 8 small 250ml bottles for processing 1 liter
tanks i think use those bottles as one shots. It's worth it. Mark
_________________________________________


 The popular dilution on the lug for Xtol is 1:3. This will give you
more sharpness and edge effects then 1:2 or 1:1 or certainly straight.
It will still give you almost invisible grain with most films. Any grain
you DO see with be tight and regular. So Give the 1:3 a try and see how
you like it. It is raved about often here on the Lug and mentioned in
"The Film Developing Cookbook" by Anchell Troop; a LUG Bible… perhaps
pour out your Xtol into 250 ml bottles to use as one-shots. You don't
want air touching your Xtol during storage. Don't get the one liter
packets, get the 5 liter packets. The negs from 1:3 are very easy to
print. Very smooth. 
> You use metal tanks and reels? I commonly run 4 reels in a liter metal
> tank and have no problem.
> 
> By the way I do like Delta but have swithced to Neopan films. The 100,
> 400 and 1600.

_______________________________________________________


 I'm at 1:3 as i just posted but now I'm reading this... with a metal
tank and reels each reel gets a quarter of a liter; 250 mls so at 1:3
like I use that's 62.5 mls of Xtol. A bit below your 75 mls... so
something funny is going on. Five liter packet? glass bottles none kept
partially filled? 1:2 with my metal tanks and reels would delelver 83.3
of Xtol 1:1 with my metal tanks and reels would delelver 125 of Xtol


By the way, it's iron in the water that might be the culprit for
problems. If you know you have lots of iron in your water (how would you
know that?!) then don't even TRY not using distilled water. Although
Iron might be one of the more easy things an on line filter takes out. I
have on line filters i got from Calumet. (Which I've always thought of
as a photo plumbing store)

 Also it is important i think to mix up your chemicals not in very hot
water but in the range listed on the packet. If you get much hotter than
the hottest recommended I can see how that would not be good for
Ascorbic acid derivatives. IK put mine in the middle of the range but i
cant recall what that temperature is. I've been using Xtol for three and
a half years and no problems, certainly no "failures." My Xtol is stored
in small brown glass bottles filled to the top with no air pockets right
under the cap. And in filtered Portland Water which is pretty good water
to the extent that it is pretty foolish to buy those bottled waters
here. Unless like me you've got lead pipes. My condolences. But I'm not
completely sure this is "Xtol failure." Nor am I sure there is such a
thing. Xtol needs to be handled in ways people who are used to D76 have
trouble coming to terms with. I think there may be a reason for the Xtol
to have oxidized. I tend to think like that. Things happen for reasons.
If it was D76 when it was dead it would be brown. You'd not use it then.
It would not have failed you and your film. But as it's Xtol
interestingly it stays perfectly clear. And that's most of the problem.
Xtol sure fails to warn us it had oxidized or died for whatever reason!
But those reasons eventually present themselves from all the people I've
talked to and pretty quick. At least so far.

_________________________ 

Notice for a liter tank filled with 35mm rolls I'm only getting 62.5 mls
of Xtol per roll! For a few years now. The Kodak swat team (yellow
jumpsuits and red baseball hats) have not broken down my door yet! It's
possible my times are a few minutes more than what Kodak are. I'm at
near exhaustion with my developer which is a good thing. By the way this
WAS a problem also with Delta 3200 which i know go 1;1 on But i have had
great luck with 62.5 mls per roll which is 1:3 with Delta 400(older) and
100. Tri X. Tri X professional and Plus X professional, Neopan 100, 400
and 1600. I'd be amazed in a conflict with Agfa films and the other
older Ilford films. Sharp excellent negs and if you read the Anchell and
Troop stuff and some other stuff it seems to be the "classic" dilution
the better smarter people are using. It's the most you can dilute
without running into trouble which is generally the way to go. The most
you can dilute without getting into too much grain or un even
development. Or loss of film speed. You get excellently optimal
compensation at this dilution. The highlights don't block up while the
shadows can contine to build up density throughout your development
cycle; till you agitate again. This translates to maximum film speed.
Which tends to be the speed indicated on the outside of the box, no more
or less.


Mark Rabiner
Portland, Oregon USA
http://www.rabinergroup.com
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In reply to: Message from Tim Atherton <tim@KairosPhoto.com> ([Leica] Mark Rabiner's Xtol instructions)